One of the most common Nmap usage scenarios is scanning an Ethernet LAN. Most LANs, especially those that use the private address range granted by RFC 1918, do not always use the overwhelming majority of IP addresses. When Nmap attempts to send a raw IP packet, such as an ICMP echo request, the OS must determine a destination hardware (ARP) address, such as the target IP, so that the Ethernet frame can be properly addressed. .. This is required to issue a series of ARP requests. This is best illustrated by an example where a ping scan is attempted against an Area Ethernet host. The -send-ip option tells Nmap to send IP-level packets (rather than raw Ethernet), even on area networks. The Wireshark output of the three ARP requests and their timing have been pasted into the session.
Raw IP ping scan example for offline targets
This example took quite a couple of seconds to finish because the (Linux) OS sent three ARP requests at 1 second intervals before abandoning the host. Waiting for a few seconds is excessive, as long as the ARP response usually arrives within a few milliseconds. Reducing this timeout period is not a priority for OS vendors, as the overwhelming majority of packets are sent to the host that actually exists. Nmap, on the other hand, needs to send packets to 16 million IP s given a target like 10.0.0.0/8. Many targets are pinged in parallel, but waiting 2 seconds each is very delayed.
There is another problem with raw IP ping scans on the LAN. If the destination host turns out to be unresponsive, as in the previous example, the source host usually adds an incomplete entry for that destination IP to the kernel ARP table. ARP tablespaces are finite and some operating systems become unresponsive when full. If Nmap is used in rawIP mode (-send-ip), Nmap may have to wait a few minutes for the ARP cache entry to expire before continuing host discovery.
ARP scans solve both problems by giving Nmap the highest priority. Nmap issues raw ARP requests and handles retransmissions and timeout periods in its sole discretion. The system ARP cache is bypassed. The example shows the difference. This ARP scan takes just over a tenth of the time it takes for an equivalent IP.
Example b ARP ping scan of offline target

In example b, neither the -PR option nor the -send-eth option has any effect. This is often because ARP has a default scan type on the Area Ethernet network when scanning Ethernet hosts that Nmap discovers. This includes traditional wired Ethernet as 802.11 wireless networks. As mentioned above, ARP scanning is not only more efficient, but also more accurate. Hosts frequently block IP-based ping packets, but usually cannot block ARP requests or responses and communicate over the network.Nmap uses ARP instead of all targets on equivalent targets, even if different ping types (such as -PE and -PS) are specified. LAN.. If you do not need to attempt an ARP scan at all, specify -send-ip as shown in Example a "Raw IP Ping Scan for Offline Targets".
If you give Nmap control to send raw Ethernet frames, Nmap can also adjust the source MAC address. If you have the only PowerBook in your security conference room and a large ARP scan is initiated from an Apple-registered MAC address, your head may turn to you. Use the -spoof-mac option to spoof the MAC address as described in the MAC Address Spoofing section.

WS-Address provides additional routing information in the SOAP header to support asynchronous communication. This technique allows the transmission of web service requests and response messages using different TCP connections
https://www.google.com/search?client=firefox-b-d&q=WS-Address+spoofing
CEH V11 Module 14 Page 1896