Explanation
The best option for the administrator to take would be to attempt to connect to the site via IP address. This will help to determine if the issue is related to the website's DNS address or if the site itself is not accessible.
Checking for certificate issues may be necessary, but this should be done after the administrator has attempted to connect to the site via IP address. Contacting the ISP is unnecessary since the issue is related to the website inside of the company network, and checking the NTP configuration is not relevant to this issue.
When a customer is having issues connecting to a website using a URL, one of the first troubleshooting steps a network administrator should take is attempting to connect to the site using the IP address of the website. This will help to determine if the issue is related to a DNS resolution problem or a connectivity problem. If the administrator is able to connect to the website using the IP address, then the issue may be related to a DNS problem. However, if the administrator is still unable to connect, then the issue may be related to a connectivity problem. In either case, further troubleshooting steps will be necessary. Checking for certificate issues or NTP configuration, and contacting the ISP would not be the BEST initial steps in this scenario.

See the solution configuration below in Explanation
Explanation:

VPN (Virtual Private Network) is the most appropriate way to enable secure remote printing. VPN is a technology that creates a secure and encrypted tunnel over a public network such as the Internet. It allows remote users or sites to access a private network as if they were directly connected to it. VPN can be used for various purposes such as accessing corporate resources, bypassing geo-restrictions, or enhancing privacy and security. VPN can also be used for remote printing by allowing users to connect to a printer on the private network and send print jobs securely over the VPN tunnel. Reference: https://www.cisco.com/c/en/us/support/docs/security-vpn/ipsec-negotiation-ike-protocols/14106-how-vpn-works.html

Explanation
172.19.0.2 is a valid IP address configuration for the device that uses a static RFC1918 address for the network and allows for a connection over NAT (Network Address Translation). RFC1918 addresses are private IP addresses that are not routable on the public Internet and are used for internal networks. The RFC1918 address ranges are 10.0.0.0/8, 172.16.0.0/12, and 192.168.0.0/16. NAT is a technique that translates private IP addresses to public IP addresses when communicating with external networks, such as the Internet. FE80::1 is an IPv6 link-local address that is not a static RFC1918 address and does not allow for a connection over NAT.
100.64.0.1 is an IPv4 address that belongs to the shared address space range (100.64.0.0/10) that is used for carrier-grade NAT (CGN) between service providers and subscribers, which is not a static RFC1918 address and does not allow for a connection over NAT. 169.254.1.2 is an IPv4 link-local address that is automatically assigned by a device when it cannot obtain an IP address from a DHCP server or manual configuration, which is not a static RFC1918 address and does not allow for a connection over NAT. 224.0.0.12 is an IPv4 multicast address that is used for VRRP (Virtual Router Redundancy Protocol), which is not a static RFC1918 address and does not allow for a connection over NAT.

Explanation
Based on the site survey table, we can see that AP 2, AP 3, and AP 4 are all broadcasting on the same channel, which can cause interference and affect performance. Therefore, the next step a wireless technician should take to troubleshoot this issue is to reconfigure the channels to reduce overlap. This will help to improve network performance and eliminate any interference.
References:
Network+ N10-007 Certification Exam Objectives, Objective 2.8: Given a scenario, troubleshoot common wireless problems and perform site surveys.